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51.
Motivated by the continuing interest in the tree data model, we study the expressive power of downward navigational query languages on trees and chains. Basic navigational queries are built from the identity relation and edge relations using composition and union. We study the effects on relative expressiveness when we add transitive closure, projections, coprojections, intersection, and difference; this for Boolean queries and path queries on labeled and unlabeled structures. In all cases, we present the complete Hasse diagram. In particular, we establish, for each query language fragment that we study on trees, whether it is closed under difference and intersection. 相似文献
52.
Photosynthesis is a fundamental process in biosciences and biotechnology that influences profoundly the
research in other disciplines. In this paper, we focus on the characterization of fundamental components, present in
pigment-protein complexes, in terms of their spectroscopic properties such as infrared spectra, nuclear magnetic
resonance, as well as nuclear quadrupole resonance, which are of critical importance for many applications. Such
components include chlorophylls and bacteriochlorophylls. Based on the density functional theory method, we
calculate the main spectroscopic characteristics of these components for the Fenna-Matthews-Olson light-harvesting
complex, analyze them and compare them with available experimental results. Future outlook is discussed in the
context of current and potential applications of the presented results. 相似文献
53.
AbstractThe reabsorption characteristics of the lignite treated by low and high temperature drying process were addressed in the paper. The information about the moisture form, functional groups, effective water-filled porosities and equilibrium moisture content of the lignite before and after the drying process was investigated using Differential scanning calorimetry (DSC), Fourier transform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy and a self-made reabsorption device, respectively. The results show that the low drying temperature (140, 190, 230?°C, 10?min, N2) has little impact on the effective water-filled porosities of the resulted samples, whereas it has a great influence on the main oxygen-containing functional groups, which amount firstly decreases and then increases with the drying temperature increasing. In the case of the lignite samples dried under high-temperature (600, 700, 800?°C, 30?s, N2), the amount of the effective water-filled porosity of the sample decreases and the amount of oxygen-containing functional groups increases as the temperature increasing. The reabsorption capability of the high temperature dried sample is much lower than that of the sample treated under low drying temperature. The reabsorption characteristics of the low-temperature dried samples are affected by the amount of the oxygen-containing functional groups, while the effective water-filled porosity is main factor for the lignite samples derived from high temperature drying process. Moreover, the work gives a good evidence that the high-temperature drying process is an effective choose for lignite upgrading. 相似文献
54.
《Ceramics International》2020,46(17):26637-26645
Intense research work is underway for identifying materials with potential applications in energy storage and energy harvesting systems. The magnesium based scandium chalcogenides have recently emerged as potential candidates for Mg batteries owing to their high Mg ionic conductivity and low electron conduction. At the same time, their band gaps are capable of absorbing electromagnetic radiations in visible to UV range; making them suitable for solar cell applications. In order to analyze the application of MgSc2X4(X = S, Se) compounds in energy devices, in this work we employ density functional theory calculations using the full potential linear augmented plane-wave method for examining their optoelectronic and thermoelectric properties. For the structural properties, the generalized gradient approximation functional designed for solids (PBEsol-GGA) has been used, while modified Becke and Johnson (mBJ) potential functional is used for computing the optoelectronic and transport properties. Our calculated optical properties indicate that these materials can find applications in solar cells. Moreover, the electronic transport properties computed using Boltzmann transport equation suggest carrier concentrations in MgSc2S4 to MgSc2Se4 spinels can be tuned for making them suitable for metal ion batteries. 相似文献
55.
The generic model query language GMQL is designed to query collections of conceptual models created in arbitrary graph-based modelling languages. Querying conceptual models means searching for particular model subgraphs that comply with a predefined pattern query. Such a query specifies the structural and semantic properties of the model fragment to be returned. In this paper, we derive requirements for a generic model query language from the literature and formally specify the language’s syntax and semantics. We conduct an analysis of GMQL׳s theoretical and practical runtime performance concluding that it returns query results within satisfactory time. Given its generic nature, GMQL contributes to a broad range of different model analysis scenarios ranging from business process compliance management to model translation and business process weakness detection. As GMQL returns results with acceptable runtime performance, it can be used to query large collections of hundreds or thousands of conceptual models containing not only process models, but also data models or organizational charts. In this paper, we furthermore evaluate GMQL against the backdrop of existing query approaches thereby carving out its advantages and limitations as well as pointing toward future research. 相似文献
56.
《Measurement》2015
The evaluation of functional features of manufactured workpieces is based on GO- and NO-GO-test results, which are obtained by comparing measured geometric characteristics with nominal dimensions and tolerances specified by the designer. These geometrical specifications are based on a tolerancing system, which was originally defined for the function mating capability. Against the background of upcoming lots of other new functions (like reduction of flow resistance, light absorption, reduction of friction, diffraction of light, self-cleaning or mass transmission) are to be realized with our products – particularly by micro- and nano scaled features. If the verification process will deliver the prediction of the achievable degree of functionality, the usability of a part can be assessed more accurately and in consequence quality and economics can be improved. So, a new principle for tolerancing and verifying turns out to be necessary. In this paper the fundamental deficit of the actual tolerancing and specification systems GPS and ASME Y14.5 is derived and the path for enlarging the system by preposing a functional model is shown. To verify the functional capability of the workpieces an approach based on simulations done with the parameterized mathematical–physical model of the function is suggested. Advantages of this approach will be discussed and demonstrated by examples with microstructured inking rolls, crankshafts and injection valves. 相似文献
57.
In this work, interaction nature between a group of aromatic sulfur compounds and [BMIM]+[FeCl4]− have been investigated by density functional theory (DFT). A coordination structure is found to be critical to the mechanism of extractive desulfurization. Interaction energy and extractive selectivity follow the order: thiophene (TH) < dibenzothiophene (DBT) ≈ benzothiophene (BT). Alkylation of TH or BT (e.g. 3-methylthiophene, and 3-methylbenzothiophene) leads to a stronger interaction with ionic liquid, but steric hindrance effects of some alkylic derivatives (e.g. 2,7-dimethylbenzothiophene) lead to a weaker interaction with ionic liquid. The mechanism of extractive desulfurization is attributed to the charge transfer effect. During extractive desulfurization, electrons on aromatic sulfur compounds transfer into the Lewis part of ionic liquid, namely, [FeCl4]−. Furthermore, it is better to consider the Lewis acidity of Fe-containing ionic liquid by the whole unit (such as [FeCl4]− and aromatic sulfur compounds (X)) rather than only Fe or S atom. 相似文献
58.
Functional expression and synergistic cooperation of xylan‐degrading enzymes from Hypocrea orientalis and Aspergillus niger 下载免费PDF全文
59.
Dinh Cong Huong Van Thanh Huynh Hieu Trinh 《International Journal of Adaptive Control and Signal Processing》2020,34(9):1281-1293
This article considers the design of interval functional observers to estimate a linear function of the state vector of time-delay systems subject to both input and output additive disturbances. Two novel functional observers are proposed and designed such that they bound the set of all admissible values of a linear function of the state vector at each instant of time. By contrast to interval observers currently available in the literature, both observers proposed in this article utilize multiple delayed output measurement and have a more general structure. This trade-off feature overcomes some drawbacks in previous work and enables interval functional observers to be designed for a wider class of time-delay systems. Conditions for the existence of interval functional observers are derived and an effective design algorithm for computing unknown observer matrices is provided. Two illustrative examples are given to show the advantages and effectiveness of our design method. 相似文献
60.
在工程实践中,为了解决存在的技术问题,需要对现有产品进行创新设计,针对产品创新设计中普遍存在的专利规避需求,结合TRIZ建立了专利规避设计流程,包括规避问题的提出、规避对象的确定和规避设计;以FDM技术为例,对造成FDM技术成型精度低和打印速度慢的问题进行分析,并结合问题原因,专利检索到了在保证打印精度的前提下提高打印速度的技术方案,通过技术迁移,建立了迁移后的初始模型,并利用TRIZ中的功能裁剪进行了专利规避设计和侵权判定,可为企业及研究机构利用专利信息实施专利规避设计提供参考。 相似文献